4-Chloro-N′-(2-hydroxy-4-methoxybenzylidene)benzohydrazide methanol monosolvate

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4-Chloro-N′-(2-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide methanol monosolvate

The title compound, C(15)H(13)ClN(2)O(3)·CH(3)OH, was synthesized by the condensation reaction of 2-hy-droxy-4-meth-oxy-benzaldehyde with 4-chloro-benzohydrazide in methanol. The Schiff base mol-ecule displays a trans configuration with respect to the C=N and C-N bonds. The dihedral angle between the two benzene rings is 5.3 (2)°. In the crystal, mol-ecules are linked by N-H⋯O and O-H⋯O hydroge...

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4-Chloro-N′-(4-meth­oxy­benzyl­idene)benzohydrazide methanol monosolvate

The title compound, C(15)H(13)ClN(2)O(2)·CH(4)O, consists of a 4-chloro-N'-(4-meth-oxy-benzyl-idene)benzohydrazide (CMB) mol-ecule and a methanol mol-ecule of crystallization. It was obtained by the condensation of 4-meth-oxy-benzaldehyde with 4-chloro-benzohydrazide. In the CMB mol-ecule, the dihedral angle between the two benzene rings is 50.1 (3)°. The methanol mol-ecule is linked to the CMB...

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N′-(4-Diethyl­amino-2-hy­droxy­benzyl­idene)-4-(dimethyl­amino)­benzo­hydrazide methanol monosolvate

The title compound, C(20)H(26)N(4)O(2)·CH(3)OH, was prepared by the reaction of 4-diethyl-amino-2-hy-droxy-benzaldehyde with 4-(dimethyl-amino)-benzohydrazide. The dihedral angle between the two benzene rings is 13.6 (3)° and an intra-molecular O-H⋯N hydrogen bond generates an S(6) ring. In the crystal, the hydrazone and methanol mol-ecules are linked through inter-molecular O-H⋯O and N-H⋯O hyd...

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4-Dimethyl­amino-N′-(2-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide methanol monosolvate

The asymmetric unit of the title compound, C(17)H(19)N(3)O(3)·CH(4)O, comprises two Schiff base mol-ecules and two methanol solvent mol-ecules. The Schiff base mol-ecules are approximately planar, with r.m.s. deviations from the planes defined by the non-H atoms of 0.107 and 0.154 Å, and with dihedral angles between the benzene rings of 4.49 (15) and 8.39 (15)°, respectively. This near-planarit...

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N′-(5-Bromo-2-hy­droxy­benzyl­idene)-4-nitro­benzohydrazide methanol monosolvate

In the title compound, C(14)H(10)BrN(3)O(4)·CH(4)O, the benzohydrazide mol-ecule is nearly planar [maximum deviation = 0.110 (2) Å]. The mean planes of the two benzene rings make a dihedral angle of 8.4 (3)°. In the benzohydrazide mol-ecule, there is an intra-molecular O-H⋯N hydrogen bond and the NH group is hydrogen bonded to the methanol solvent mol-ecule. In the crystal, inter-molecular O-H⋯...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2011

ISSN: 1600-5368

DOI: 10.1107/s1600536811039778